Tetrahedron Letters p. 7013 - 7016 (1991)
Update date:2022-08-02
Topics:
Givens, Richard S.
Singh, Rominder
Initial bond breaking processes (homolysis vs heterolysis) of phosphate ester photosolvolysis were probed by chemically trapping the reactive intermediates with a tethered 5-hexenyl group. The resulting mechanistic picture is a blend of homolytic and heterolytic pathways, where the heterolytic cleavage is dominant.
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