A Catalytic Asymmetric Synthesis of α-Methylene Lactones by the Palladium-catalysed Carbonylation of Prochiral Alkenyl Halides

DOI: 10.1039/c39910001593

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1593 - 1595 (1991)

Update date:2022-07-29

Topics:

Authors:

Suzuki, Takeyuki

Uozumi, Yasuhiro

Shibasaki, Masakatsu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39910001593

A catalytic asymmetric synthesis of the α-methylene lactones starting with the prochiral alkenyl halides 8 and 19 has been achieved for the first time, giving 9 in 57percent enantiomeric excess (e.e.) and 20 in 39percent e.e., respectively.

Full text of DOI:10.1039/c39910001593

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(3aS,4S,6aR)-4-Hydroxy-3a-methyl-3-methylene-hexahydro-cyclopenta[b]furan-2-one

Cas No:138812-27-8

R&D Labs maybe for 138812-27-8

SHAANXI TOP PHARM CHEMICAL CO.LTD

Contact:+86-029-85733403

Address:No.108 ,west sector,south er huan,xi'an,china
GIHI CHEMICALS CO.,LIMITED

Contact:+86-571-86217390

Address:No.567 Dengcai Street,Sandun,Westlake District,Hangzhou310030,Zhejiang,China.
Shanghai Coupling Pharmaceutical R&D Co., Ltd.(expird)

Contact:+86 021 50106671

Address:403 Room No.4 Buiding, No. 526 Ruiqing Road, Shanghai Zhangjiang Hi-Tech Park
Ji'nan Orgachem Pharmaceutical Co.,Ltd

Contact:+86-531-82687810

Address:Jinan
ShangHai BMG Chemical Co., Ltd

Contact:+86-13524845543

Address:Room 602, no 291 sikai road shanghai

Relevant to this article

Reaction of iodo(trimethyl)silane with N,N-dimethyl carboxylic acid amides

Doi:10.1134/S1070428010060035
(2010)
3-Hydroxypyrroles and 1H-Pyrrol-3(2H)-ones. Part 10. Alkylation of Pyrrolones under Basic Conditions: Regiospecific Formation of 3-Alkoxypyrroles

Doi:10.1039/P19910003245
(1991)
Anion complexation by bidentate Lewis acidic hosts, ortho-bis(fluorosilyl) benzenes

Doi:10.1016/0022-328X(95)05636-4
(1996)
Doi:10.1007/BF00899223
()
Mechanistic Aspects and Synthetic Applications of the Electrochemical and Iodobenzene Bis(trifluoroacetate) Oxidative 1,3-Cycloadditions of Phenols and Electron-Rich Styrene Derivatives

Doi:10.1021/jo00033a040
(1992)
Covalent Triazine Framework Nanoparticles via Size-Controllable Confinement Synthesis for Enhanced Visible-Light Photoredox Catalysis

Doi:10.1002/anie.202007358
(2020)

Article Doi