Chemistry Letters p. 1257 - 1259 (2011)
Update date:2022-08-04
Topics:
Matsuda, Masaki
Ohishi, Hiroko
Tofuku, Madoka
Muramoto, Naho
Yamaura, Jun-Ichi
A molecular conductor based on axially CN-substituted cobalt tetrabenzoporphyrin is reported. The crystal structure is isomorphous with a phthalocyanine-based conductor, however, estimation of effectiveness of π-π overlap and electrical transport measurement reveal that a slight change in molecular structure of macrocyclic π-conjugated ligands has significant influence on intermolecular interaction and electrical properties.
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