Organometallics p. 2934 - 2938 (1992)
Update date:2022-07-29
Eagle, Aston A.
Young, Charles G.
Tiekink, Edward R. T.
Reaction of WO2Cl2 with K{HB(Me2pz)3} [HB-(Me2pz)3- = hydrotris(3,5-dimethyl-1-pyrazolyl)borate anion] in N,N-dimethylformamide produces cis-{HB-(Me2pz)3}WO2Cl (1), which reacts with Grignard reagents in tetrahydrofuran to yield the organometallic dioxo-W(VI) complexes cis-{HB(Me2pz)3}WO2(R) (R = Me (2), Et (3), CH2Ph (4). Ph (5)). The X-ray structures of 3 and 5 reveal that the monomerlc complexes possess distorted-octahedral coordination spheres composed of a facially tridentate HB(Me2pz)3- ligand, two terminal oxo ligands, and an n1-hydrocarbyl group.
View MoreHebei Lead Bio-Chemicals Co., Ltd.
website:http://www.ldbiochem.com
Contact:+86-311-87826503
Address:481, Heping West Road, Shijiazhuang,China
Contact:18669908765
Address:Zibo City, Shandong Province, P.R.China
Jintan Jinnuo Chemical Co., Ltd.
Contact:+86-519-80199901
Address:Room 1804, Building 1, Huacheng Business Plaza, Jintan, Jiangsu, China
BrightGene Bio-Medical Technology Co., Ltd.
website:https://en.bright-gene.com/
Contact:+86-512-62551801
Address:Building C25 - C31, No. 218 Xinghu Road, Suzhou Industrial Park, Suzhou, Jiangsu, China.
Beijing ZhongDaXinHe Chemical Product Co.,Ltd(expird)
Contact:010-52876516
Address:tongzhoubeiyuan
Doi:10.1248/cpb.39.3370
(1991)Doi:10.1007/s00044-011-9752-8
(2012)Doi:10.1002/1521-3773(20021018)41:20<3852::AID-ANIE3852>3.0.CO;2-I
(2002)Doi:10.1016/j.bmcl.2012.05.080
(2012)Doi:10.1007/BF01666725
(1994)Doi:10.1039/c2ob25647a
(2012)
