Organometallics p. 2934 - 2938 (1992)
Update date:2022-07-29
Eagle, Aston A.
Young, Charles G.
Tiekink, Edward R. T.
Reaction of WO2Cl2 with K{HB(Me2pz)3} [HB-(Me2pz)3- = hydrotris(3,5-dimethyl-1-pyrazolyl)borate anion] in N,N-dimethylformamide produces cis-{HB-(Me2pz)3}WO2Cl (1), which reacts with Grignard reagents in tetrahydrofuran to yield the organometallic dioxo-W(VI) complexes cis-{HB(Me2pz)3}WO2(R) (R = Me (2), Et (3), CH2Ph (4). Ph (5)). The X-ray structures of 3 and 5 reveal that the monomerlc complexes possess distorted-octahedral coordination spheres composed of a facially tridentate HB(Me2pz)3- ligand, two terminal oxo ligands, and an n1-hydrocarbyl group.
View MoreGuangxi Bonger Pharmaceutical Co., Ltd
website:http://napo.lookchem.com/
Contact:+86-18817331185
Address:Donghai Industrial Zone, Tiandong Country,Guangxi,China
Contact:86-571-87758773
Address:Room604 ,6F, Block A1-3 Xixi Plaza,No. 588 Wenyi West RD, Hangzhou,310012, China
ZhangJiaGang YaRui Chemical Co.,Ltd.
Contact:0512-58360968
Address:China JiangSu Province Zhang Jia Gang City YangShe Oriental Plaza Building 10 B307
Zhejiang kehong chemical co., ltd
Contact:0086-575-85522000
Address:xiner center RD binhai industrial zone shaoxing zhejiang province P.R.China,312073
Nantong Auxin Electronic Technology Co., LTD
Contact:86-513-88760026
Address:NO.5-1, Aoxin Road, Haian Hi-tech Development Zone, Jiangsu Province, China
Doi:10.1248/cpb.39.3370
(1991)Doi:10.1007/s00044-011-9752-8
(2012)Doi:10.1002/1521-3773(20021018)41:20<3852::AID-ANIE3852>3.0.CO;2-I
(2002)Doi:10.1016/j.bmcl.2012.05.080
(2012)Doi:10.1007/BF01666725
(1994)Doi:10.1039/c2ob25647a
(2012)
