Cu-Catalyzed C-H Trifluoromethylation of 3-Arylprop-1-ynes for the Selective Construction of Allenic Csp2-CF3 and Propargyl Csp3-CF3 Bonds

DOI: 10.1021/acs.orglett.6b00120

Source and publish data:

Organic Letters p. 1000 - 1003 (2016)

Update date:2022-08-04

Topics:

Authors:

Ji, Yun-Long

Luo, Jia-Jia

Lin, Jin-Hong

Xiao, Ji-Chang

Gu, Yu-Cheng

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/acs.orglett.6b00120

A new method has been developed for the Cu-catalyzed C-H trifluoromethylation of 3-arylprop-1-ynes for the selective construction of allenic Csp²-CF₃ and propargyl Csp³-CF₃ bonds. The selective formation of alle

Full text of DOI:10.1021/acs.orglett.6b00120

Products guided by the article

Product name:1-(tert-butyl)-4-(4,4,4-trifluorobuta-1,2-dien-1-yl)benzene

Cas No:1390640-17-1

R&D Labs maybe for 1390640-17-1

CHANGYI CITY FENGRUN FINE CHEMICAL CO.,LTD

website:http://www.fengrunhuagong.com

Contact:+86-536-7869976

Address:Changyi Coastal Economic Development Zone
Jiangsu Jiuri Chemical Co.,Ltd.

Contact:+86-519-82118868

Address:Tianwang Town, Jurong City, Jiangsu Province, China
Shandong united-rising pharmaceutical cooperation.,ltd.

Contact:008653187965009

Address:171No., Jing5 Road, Shizhong District, Jinan, China
enantiotech corporation ltd

Contact:+86-0760-85282375

Address:zhongjing road,zhongshan torch hi-tech industrial development zone
Hubei Xinjing New Material Co.,Ltd

Contact:+86-27-83313147

Address:Room402.#Bthe 7th,Headquarter of Huifeng Corporation Qiaokou District,Wuhan China

Relevant to this article

Rhodium-catalyzed carbonylative [3 + 2 + 1] cycloaddition of alkyne-tethered alkylidenecyclopropanes to phenols in the presence of carbon monoxide

Doi:10.1021/ol5015224
(2014)
Specific cell surface protein imaging by extended self-assembling fluorescent turn-on nanoprobes

Doi:10.1021/ja304239g
(2012)
Syntheses of_DL-2-fluoromethy-_P-tyrosine and_DL-2-difluoromethyl-_P-tyrosine as potential inhibitors of tyrosine hydroxylase

Doi:10.1016/S0040-4039(00)92112-9
(1991)
Investigation of the reaction of dithiocarbamic acid salts with aromatic aldehydes

Doi:10.1021/ol301598u
(2012)
Expedient N-arylation for the synthesis of 2-arylamino-3-cyanopyridines using ionic copper(I) complex as a catalyst

Doi:10.3987/COM-12-12461
(2012)
Photodegradable macromers and hydrogels for live cell encapsulation and release

Doi:10.1021/ja305280w
(2012)

Article Doi