Total synthesis of queen substance of honeybee using an organosilicon route

DOI: 10.1016/0040-4039(91)80490-W

Source and publish data:

Tetrahedron Letters p. 7253 - 7254 (1991)

Update date:2022-07-30

Topics:

Authors:

Bellassoued

Majidi Majidi

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Article abstract of DOI:10.1016/0040-4039(91)80490-W

O-silylated enolates are used as the key intermediates in the total synthesis of queen substance. The synthesis proceeds in 7 steps and affords the desired pheromone with very high stereoselectivity and 34% overall yield.

Full text of DOI:10.1016/0040-4039(91)80490-W

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