Highly stereoselective glycosylation by conformational assistance of glycosyl donor

DOI: 10.1016/0040-4039(91)80435-9

Source and publish data:

Tetrahedron Letters p. 6887 - 6890 (1991)

Update date:2022-08-04

Topics:

Authors:

Toshima, Kazunobu

Nozaki, Yuko

Tatsuta, Kuniaki

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Article abstract of DOI:10.1016/0040-4039(91)80435-9

Highly α-stereoselective glycosylation of 2-deoxy-D-fucose was achieved by use of the conformational assistance of the rigid glycosyl donor 2. The selectivity of the glycosylation of 2 was much higher than that of 3 which had a normal chair conformation.

Full text of DOI:10.1016/0040-4039(91)80435-9

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