Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 2196 - 2204 (1991)
Update date:2022-08-04
Topics:
Ivanova, N. M.
Cheskis, B. A.
Moiseenkov, A. M.
Nefedov, O. M.
The title linear acetogenins have been synthesized by a strategy of joining acetylcyclopropane to 8Z-tridecenol or 5Z-decenol prepared after Julia, leading to the corresponding secondary cyclopropylcarbinols.The ZnBr2/Me3SiBr-initiated homoallylic rearrangement of the latter assures at a key step the stereospecific construction of transoid fragments of the target molecules.
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