Asymmetric intramolecular Diels-Alder reaction of a sulphoximine-substituted triene

DOI: 10.1016/S0957-4166(00)80016-6

Source and publish data:

Tetrahedron Asymmetry p. 1177 - 1180 (1991)

Update date:2022-09-26

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Authors:

Craig Craig

Geach Geach

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Article abstract of DOI:10.1016/S0957-4166(00)80016-6

The synthesis and thermally-induced intramolecular Diels-Alder (IMDA) reaction of (S)(S)-(+)-S-[(1E,7E)-1,7,9-decatrienyl]-S-phenyl-N-(p-tolylsulphonyl) sulphoximine 4 is described. A model is proposed for the cis-selectivity of the cycloaddition based on

Full text of DOI:10.1016/S0957-4166(00)80016-6

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