A Novel Approach to α-Silylmethylene-β-lactams via Rh-catalyzed Silylcarbonylation of Propargylamine Derivatives

DOI: 10.1016/0040-4039(91)80126-Q

Source and publish data:

Tetrahedron Letters p. 7431 - 7434 (1991)

Update date:2022-07-29

Topics:

Authors:

Matsuda, Isamu

Sakakibara, Jun

Nagashima, Hideo

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Article abstract of DOI:10.1016/0040-4039(91)80126-Q

α-Silylmethylene-β-lactams are successfully constructed by the one-pot coupling of a substituted propargylamine derivative, a triorganosilane, and CO with the catalysis of Rh4(CO)12 and DBU.

Full text of DOI:10.1016/0040-4039(91)80126-Q

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Product name:Carbamic acid, [1-[2-(dimethylphenylsilyl)-1-formylethenyl]cyclohexyl]-, methyl ester, (Z)-

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