Ipso Selectivity in the Reductive Iodonio-Claisen Rearrangement of Allenyl(p-methoxyaryl)iodinanes

DOI: 10.1039/c39920000015

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 15 - 16 (1992)

Update date:2022-08-05

Topics: Reductive Iodonio-Claisen Rearrangement Experimental terms

Authors:

Ochiai, Masahito

Ito, Takao

Masaki, Yukio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39920000015

Allenyl(aryl)iodinanes, generated from p-methoxy(diacetoxyiodo)arenes by the reaction with propyn-2-yl(trimethyl)silanes in the presence of BF3-Et2O in dichloromethane, undergo reductive ipso iodonio-Claisen rearrangement selectively at -20 deg C yielding

Full text of DOI:10.1039/c39920000015

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:4-Hexyn-3-ol, 6-(4-methoxy-2,6-dimethylphenyl)-2-methyl-

Cas No:139553-90-5

R&D Labs maybe for 139553-90-5

Wuhan Yitongtai Science and Technology Co.,Ltd.

Contact:+86-27-88933550

Address:27th Fl. Bldg. 1, Shuian International Mansion, Heping Ave, Wuhan, Hubei, China
Xiamen XM-Innovation Chemical Co., Ltd

Contact:+86-592-3216205

Address:Unit Q, 11/F, No.1 Office Building, Wuyuan Bay Business Center, Huli District, Xiamen City, Fujian Province, P.R.C
Xiamen Hisunny Chemical Co.,Ltd

website:http://www.hisunnychem.com

Contact:+86-592-3327115

Address:Unit 603,No.879,Xiahe Road,Meixin Building,Xiamen,China
shanghai payne pharm co.,ltd.

Contact:+86-021-58123769

Address:No.780 of Cailun Road,Zhangjiang Hi-tech Park,Pudong,Shanghai
KINHENG CHEMICAL(SHANGHAI)CO., LTD.

Contact:+8621-60490170

Address:Room401, No.28,Lane 189, Yangshupu Rd. Shanghai, China.

Relevant to this article

Rapid and efficient radiosyntheses of meta-substituted [ ¹⁸F]fluoroarenes from [¹⁸F]fluoride ion and diaryliodonium tosylates within a microreactor

Doi:10.1002/ejoc.201100382
(2011)
Synthesis and reactivity of allyl samarium complexes

Doi:10.1016/S0040-4039(00)74845-3
(1991)
IPy₂BF₄-mediated rearrangements of 1,2-difunctionalized compounds and olefins

Doi:10.1002/chem.200500070
(2005)
Nickel-catalyzed formation of cyclopentenone derivatives via the unique cycloaddition of α,β-unsaturated phenyl esters with alkynes

Doi:10.1021/ja2059999
(2011)
Nickel(0)-catalyzed enantioselective annulations of alkynes and arylenoates enabled by a chiral NHC ligand: Efficient access to cyclopentenones

Doi:10.1002/anie.201408364
(2014)
Synthesis, biological evaluation, and molecular modeling of cinnamic acyl sulfonamide derivatives as novel antitubulin agents

Doi:10.1016/j.bmc.2011.06.088
(2011)

Article Doi