Ipso Selectivity in the Reductive Iodonio-Claisen Rearrangement of Allenyl(p-methoxyaryl)iodinanes

DOI: 10.1039/c39920000015

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 15 - 16 (1992)

Update date:2022-08-05

Topics: Reductive Iodonio-Claisen Rearrangement Experimental terms

Authors:

Ochiai, Masahito

Ito, Takao

Masaki, Yukio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39920000015

Allenyl(aryl)iodinanes, generated from p-methoxy(diacetoxyiodo)arenes by the reaction with propyn-2-yl(trimethyl)silanes in the presence of BF3-Et2O in dichloromethane, undergo reductive ipso iodonio-Claisen rearrangement selectively at -20 deg C yielding

Full text of DOI:10.1039/c39920000015

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:4-Hexyn-3-ol, 6-(4-methoxy-2,6-dimethylphenyl)-2-methyl-

Cas No:139553-90-5

R&D Labs maybe for 139553-90-5

Shandong Xiangde Biotechnology Co., Ltd

Contact:+86 -15066639877

Address:Sanba street
Wuhan Soleado Technology Co.,Ltd.

Contact:86-2783341481 18971291927

Address:RM2405 Unit 1 Builing 1, Taiyin Tower, Changqing Road,Wuhan China
Nanjing Fubang Chemical Co.,Ltd

Contact:+86-25-83179199

Address:5F,Tianzheng international plaza,No399 Zhongyang Road ,Nanjing China
Changzhou Ansciep Chemical Co.,Ltd.

Contact:+86 519 8630 5871

Address:A-710 Boan International, 8 East Guangdian Road,Wujin,Changzhou
Lonwin Chemical Group Limited

website:http://www.lonwinchem.com

Contact:Tel: 86-21-59858395

Address:No#966,Huaxu Road,Shanghai 201702,P.R.China

Relevant to this article

Rapid and efficient radiosyntheses of meta-substituted [ ¹⁸F]fluoroarenes from [¹⁸F]fluoride ion and diaryliodonium tosylates within a microreactor

Doi:10.1002/ejoc.201100382
(2011)
Synthesis and reactivity of allyl samarium complexes

Doi:10.1016/S0040-4039(00)74845-3
(1991)
IPy₂BF₄-mediated rearrangements of 1,2-difunctionalized compounds and olefins

Doi:10.1002/chem.200500070
(2005)
Nickel-catalyzed formation of cyclopentenone derivatives via the unique cycloaddition of α,β-unsaturated phenyl esters with alkynes

Doi:10.1021/ja2059999
(2011)
Nickel(0)-catalyzed enantioselective annulations of alkynes and arylenoates enabled by a chiral NHC ligand: Efficient access to cyclopentenones

Doi:10.1002/anie.201408364
(2014)
Synthesis, biological evaluation, and molecular modeling of cinnamic acyl sulfonamide derivatives as novel antitubulin agents

Doi:10.1016/j.bmc.2011.06.088
(2011)

Article Doi