Tetrahedron Letters p. 629 - 630 (1991)
Update date:2022-08-05
Topics:
Collin
Bied
Kagan
Allyl chlorides react with SmCp2 to afford an allyl samarium intermediate, the η3-allyl structure of which has been tentatively assigned upon its reactivity with ketones. Synthesis of β,γ-unsaturated ketones have been also performed by reacting allyl samarium compounds with acid chlorides.
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Doi:10.1021/acs.orglett.0c01208
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