Carbohydrate Research p. 29 - 36 (1986)
Update date:2022-08-04
Topics: Isomerization evidence Hydroxide-Catalyzed
King-Morris, Melinda J.
Serianni, Anthony S.
The KOH-catalyzed isomerization of D-(1-13C)mannose under anaerobic conditions was studied by 13C-n.m.r. spectroscopy.D-(1-13C)Glucose and D-(1-13C)fructose are generated during the reaction, as expected.In addition, however, (6-13C)glucose, (6-13C)mannose, and (6-13C)fructose are produced in small proportions, possibly via symmetrical 3,4-enediol intermediates.The involvement of the latter structures in 13C-label shifting is inferred from the observation of (1-13C)sorbose and (6-13C)sorbose in the reaction mixture.
View MoreOren Hydrocarbons (Qingdao) Co., Ltd.
Contact:+86-532-68607667-801
Address:Room 3 # 302, No.9 Qingyun Road, Qingdao, China
Shanghai Massive Chemical Technology Co., Ltd.
website:http://www.massivechem.com/
Contact:+86 21 34943721
Address:Room 435, 4th floor, Building 9, No. 2568 Gudai Road,Minhang District, Shanghai,
Contact:+86-532-80762375
Address:No. 6, Hongkong Middle Road, Qingdao, China
ShangHai Original Economy-Trade Develop Co.,Ltd.,
Contact:86-21-68552131
Address:shanghai
Contact:+86-532-80762375
Address:No. 6, Hongkong Middle Road, Qingdao, China
Doi:10.1002/adsc.201800333
(2018)Doi:10.1002/cmdc.201200184
(2012)Doi:10.1021/jo00094a056
(1994)Doi:10.1021/acs.jmedchem.7b01664
(2018)Doi:10.1039/c2cc34803a
(2012)Doi:10.1002/chem.201200591
(2012)
