Angewandte Chemie - International Edition p. 8378 - 8382 (2012)
Update date:2022-08-04
Topics:
Roithová, Jana
Janková, ?těpánka
Ja?íková, Lucie
Váňa, Ji?í
Hybelbauerová, Simona
The gold(I)-mediated reaction between an internal alkyne and methanol proceeds by a dual activation mechanism, which directly results in formation of gem-diaurated intermediates. Reaction intermediates were investigated by IR multiphoton dissociation spectroscopy, kinetics by NMR spectroscopy, and the mechanism by DFT calculations. Copyright
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Doi:10.1246/bcsj.20190255
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(2012)
