THE STEREOSELECTIVE SYNTHESIS OF (+/-)-9βH-PIMARA-7,19-DIENE

DOI: 10.1016/S0040-4020(01)80107-1

Source and publish data:

Tetrahedron p. 2773 - 2776 (1989)

Update date:2022-08-04

Topics:

Authors:

Jansen, Ben J. M.

Schepers, Gert C.

Groot, Aede de

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Article abstract of DOI:10.1016/S0040-4020(01)80107-1

The trans-syn-cis tricyclic system, present in (+/-)-9βH-pimara-7,19-diene (8) was formed via a Diels-Alder reaction of enone aldehyde 2 with 2-(tert-butyldimethylsilyloxy)-3-methyl-1,3-butadiene.The resulting regiospecific silyl enol ether was deformylat

Full text of DOI:10.1016/S0040-4020(01)80107-1

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