
Journal of the Chemical Society. Chemical communications p. 217 - 219 (1992)
Update date:2022-08-06
Topics:
Shin, Hyun-K.
Hampden-Smith, Mark J.
Kodas, Toivo T.
Rheingold, Arnold L.
The fluorinated β-ketoimines, 4-(alkyl)imino-1,1,1,1,5,5,5-hexafluoropentan-2-one, where alkyl = isopropyl 3 or trifluoroethyl 6, have been obtained in high yield from the reaction of a silyl ether of hexafluoroacetylacetone with isopropylamine and trifluoroethylamine, respectively, and used to prepare volatile, monomeric copper(I) β-ketoiminate complexes.
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