Synthesis of Tricarbonyl(vinylallene)iron(0) Complexes from Tricarbonyl(vinylketene)iron(0) Complexes and their Oxidation to 5,5-Disubstituted Furan-2(5H)-ones

DOI: 10.1039/P19920000259

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 259 - 266 (1992)

Update date:2022-08-04

Topics:

Authors:

Saberi, Stephen P.

Thomas, Susan E.

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Article abstract of DOI:10.1039/P19920000259

Addition of phosphonoacetate anions to tricarbonyl(vinylketene)iron(0) complexes gave tricarbonyl(vinylallene)iron(0) complexes.Stereoselectivity as high as 98:2 was observed and the relative stereochemistry of the major stereoisomers was elucidated by X-

Full text of DOI:10.1039/P19920000259

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