Stereoselective synthesis of 2-functionalized 1-bromo-1-iodo-1-alkenes by electrophilic iodination of 1-bromo-1-alkynes

DOI: 10.1055/s-1992-26086

Source and publish data:

Synthesis p. 270 - 272 (1992)

Update date:2022-07-31

Topics:

Authors:

Barluenga

Rodriguez

Campos Campos

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1992-26086

1-Bromo-1-alkynes 1 react with bis(pyridine)iodine(1) tetrafluoroborate (2) and nucleophiles (AcOH, HCO₂H, Cl^-, Br^-, I^-) to give in a stereoselective addition 2-functionalized 1-bromo-1-iodo-1-alkenes 3.

Full text of DOI:10.1055/s-1992-26086

Products guided by the article

Product name:Benzene, (2-bromo-1,2-diiodoethenyl)-, (Z)-

Cas No:140868-90-2

R&D Labs maybe for 140868-90-2

Hangzhou Zhenghan Biological Technology Co., Ltd.

Contact:86-571-88781753

Address:liangzhu yuhang hangzhou city
GUANGZHOU MEDCAN PHARMATECH LTD

website:http://www.gzmedcan.com

Contact:+86-20-82519649

Address:Building J,Room 101,1 JiangtashanRd,Guang Zhou Science City,Guang Zhou ,China
Hangzhou Haiqiang Chemical Co.,Ltd.

Contact:+86-571-86960370

Address:Add: 5/F, Around Town North Road,No. 10, Hangzhou, Zhejiang,China
SHANGHAI RC CHEMICALS CO.,LTD.

website:http://www.rcc.net.cn

Contact:+86-21-50322175

Address:Rm1415 Yinqiao Masion No.58 Jinxin Road Pudong Shanghai China
Tocopharm Co., Ltd.

Contact:+86-021-6989-5597

Address:No.80 Yichuan Rd., Putuo District,Shanghai,P.R.China

Relevant to this article

Synthesis, structures and antibacterial activities of benzoylthiourea derivatives and their complexes with cobalt

Doi:10.1016/j.jinorgbio.2012.08.001
(2012)
Synthesis of carminic acid, the colourant principle of cochineal

Doi:10.1039/a705145j
(1998)
Unexpected conversion of alkyl azides to alkyl iodides and of aryl azides to N-tert-butyl anilines

Doi:10.1016/j.tet.2012.09.066
(2012)
Efficient asymmetric Baeyer-Villiger oxidation of prochiral cyclobutanones using new polymer-supported and unsupported chiral co(salen) complexes

Doi:10.1007/s12039-012-0277-6
(2012)
Novel, Self-Assembling Dimeric Inhibitors of Human β Tryptase

Doi:10.1021/acs.jmedchem.9b01689
(2020)
The triple role of fluoride ions in palladium-catalyzed Suzuki-Miyaura reactions: Unprecedented transmetalation from [ArPdFL₂] complexes

Doi:10.1002/anie.201107202
(2012)

Article Doi