Stereoselective synthesis of 2-functionalized 1-bromo-1-iodo-1-alkenes by electrophilic iodination of 1-bromo-1-alkynes

DOI: 10.1055/s-1992-26086

Source and publish data:

Synthesis p. 270 - 272 (1992)

Update date:2022-07-31

Topics:

Authors:

Barluenga

Rodriguez

Campos Campos

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1992-26086

1-Bromo-1-alkynes 1 react with bis(pyridine)iodine(1) tetrafluoroborate (2) and nucleophiles (AcOH, HCO₂H, Cl^-, Br^-, I^-) to give in a stereoselective addition 2-functionalized 1-bromo-1-iodo-1-alkenes 3.

Full text of DOI:10.1055/s-1992-26086

Products guided by the article

Product name:Benzene, (2-bromo-1,2-diiodoethenyl)-, (Z)-

Cas No:140868-90-2

R&D Labs maybe for 140868-90-2

Tianjin Bright Future Technology Co., Ltd

Contact:0086-22-58016666

Address:NO.136 DongTeng Lake Street Tianjin Economic and Technology Development Area,Tainjin,China
Qingzhou Baibang import and export co.,Ltd

Contact:+86-536-3265899

Address:No.338, Tuoshan Road
Tangshan Moneide Trading Co., Ltd.

Contact:+86-315-8309571

Address:2-7-420 Jidong Building Materials Commercial Center, Tangshan, Hebei, 064000 China
Wuhan Benjamin Pharmaceutical Chemical Co.,Ltd

Contact:86-27-52341789

Address:Room 1518 B suite, optical valley time square, No 111 Guanshan Road, Hongshan District,Wuhan,Hubei Province,China.
SHAANXI TOP PHARM CHEMICAL CO.LTD

Contact:+86-029-85733403

Address:No.108 ,west sector,south er huan,xi'an,china

Relevant to this article

Synthesis, structures and antibacterial activities of benzoylthiourea derivatives and their complexes with cobalt

Doi:10.1016/j.jinorgbio.2012.08.001
(2012)
Synthesis of carminic acid, the colourant principle of cochineal

Doi:10.1039/a705145j
(1998)
Unexpected conversion of alkyl azides to alkyl iodides and of aryl azides to N-tert-butyl anilines

Doi:10.1016/j.tet.2012.09.066
(2012)
Efficient asymmetric Baeyer-Villiger oxidation of prochiral cyclobutanones using new polymer-supported and unsupported chiral co(salen) complexes

Doi:10.1007/s12039-012-0277-6
(2012)
Novel, Self-Assembling Dimeric Inhibitors of Human β Tryptase

Doi:10.1021/acs.jmedchem.9b01689
(2020)
The triple role of fluoride ions in palladium-catalyzed Suzuki-Miyaura reactions: Unprecedented transmetalation from [ArPdFL₂] complexes

Doi:10.1002/anie.201107202
(2012)

Article Doi