ENE REACTION OF 2-(ALKYLTHIO)ALLYL SILYL ETHER INVOLVING A CHIRALITY TRANSFER.

DOI: 10.1016/S0040-4039(00)91616-2

Source and publish data:

Tetrahedron Letters p. 1337 - 1340 (1992)

Update date:2022-08-02

Topics:

Authors:

Tanino, Keiji

Shoda, Hisashi

Nakamura, Takashi

Kuwajima, Isao

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Article abstract of DOI:10.1016/S0040-4039(00)91616-2

A highly enantio-selective ene reaction was developed on the basis of chirality transfer.Under the influence of Me2AlCl, the reactions of various aldehydes with (S)-3-(tert-butyldimethylsiloxy)-2-(ethylthio)-1-butene which was easily prepared from (S)-eth

Full text of DOI:10.1016/S0040-4039(00)91616-2

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Product name:Benzenemethanol, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-a-[3-[[(1,1-dimethylethyl)dimethyl silyl]oxy]-2-(ethylthio)-2-butenyl]-, (S)-

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