Stereoselective Hydrogen Transfer Reactions Involving Acyclic Radicals. Tandem Substituted Tetrahydrofuran Formation and Stereoselective Reduction: Synthesis of the C17-C22 Subunit of Ionomycin

DOI: 10.1021/jo00084a040

Source and publish data:

Journal of Organic Chemistry p. 1166 - 1178 (1994)

Update date:2022-07-29

Topics:

Authors:

Guindon, Y.

Yoakim, C.

Gorys, V.

Ogilvie, W. W.

Delorme, D.

et al. et al.

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Article abstract of DOI:10.1021/jo00084a040

The tandem iodoetherification reaction and stereoselective reduction of acyclic redicals has been used in the stereocontrolled synthesis of substituted tetrahydrofurans.Such a tetrahydrofuran intermediate is regioselectively cleaved using Me2BBr to reveal

Full text of DOI:10.1021/jo00084a040

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