Chemistry Letters p. 389 - 392 (1992)
Update date:2022-08-03
Topics:
Suda, Yoshimitsu
Yago, Seiji
Shiro, Motoo
Taguchi, Takeo
Highly diastereoselective alcoholysis of ?-symmetric dicarboxylic acid anhydrides was performed using 1-phenyl-3,3-bis(trifluoromethyl)propan-1,3-diol.The importance of the geminally trifluoromethylated carbinol moiety for achieving a high degree of chiral induction was confirmed from lower diastereoselectivity with the hydroxyl protected 1,3-diol or with the similar 1,3-diols having hydrocarbon substituents instead of the trifluoromethyl group.
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