The catalytic asymmetric aldol reaction of aldehydes with unsubstituted and monosubstituted silyl ketene acetals: Formation of anti-β-hydroxy-α-methyl esters

DOI: 10.1016/S0040-4039(00)91717-9

Source and publish data:

Tetrahedron Letters p. 1729 - 1732 (1992)

Update date:2022-08-03

Topics:

Authors:

Parmee Parmee

Hong Hong

Tempkin Tempkin

Masamune

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Article abstract of DOI:10.1016/S0040-4039(00)91717-9

The title rection with unsubstituted and monosubstituted silyl ketene acetals proceeds with high enantioselectivity, and in the latter case good diastereoselectivity favoring the anti-β-hydroxy-α-methyl esters in all reported cases.

Full text of DOI:10.1016/S0040-4039(00)91717-9

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