Tetrahedron Letters p. 1611 - 1614 (1992)
Update date:2022-09-26
Topics:
Leroy, Corine
Levacher, Vincent
Dupas, Georges
Bourguignon, Jean
Quequiner, Guy
The regioselectivity of the reduction of the cyclic enamide 2a with an NADH model compound was established using a deuterated model.The geometry of the substrate seems to play a fundamental role since cyclic derivatives 2a and 2d were reduced and non cyclic derivatives 2b and 2c were not reduced.Electronic factors were also examined.Key Words: enamide, NADH model, reduction, mechanism.
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