The reaction of tris(trimethylsilyl)silane with acid chlorides

DOI: 10.1016/S0040-4039(00)91733-7

Source and publish data:

Tetrahedron Letters p. 1787 - 1790 (1992)

Update date:2022-08-03

Topics:

Authors:

Ballestri

Chatgilialoglu

Cardi Cardi

Sommazzi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)91733-7

Tris(trimethylsilyl)silane, in contrast with tributylin hydridge, reduces acid chlorides to the corresponding decarboxylated hydrocarbons via a free radical mechanism. This methodology could be a viable alternative to Barton's decarboxylation reaction.

Full text of DOI:10.1016/S0040-4039(00)91733-7

Products guided by the article

Product name:Hexanal, 6-[2,2,2-trimethyl-1,1-bis(trimethylsilyl)disilanyl]-

Cas No:141422-89-1

R&D Labs maybe for 141422-89-1

Hubei Onward Bio-Development Co., Ltd.

Contact:+86-718-8417012

Address:No.517,Shizhou Avenue,Enshi City,Hubei Province,China,445002
Tianjin Hedong Red Cliff Chemical Reagent Factory

Contact:+86-022-84780548

Address:Li Ming Zhuang Gong Ye Yuan,Dongli District,Tianjin,China
Lonzeal Pharmaceuticals Co., Ltd.

website:http://www.lonzeal.com

Contact:+86-13381011962

Address:RM 801, Yue MOMA, No. 26 Anningzhuang Rd. Haidian District, Beijing, China
Ningbo Huajia Chemicals

Contact:+86-574-87065746

Address:10th Floor, No.787 Baizhang East Road,
Shenzhen Hongyuan Import & Export Co., Ltd.

Contact:0755-26407171

Address:Shenzhen Hongyuan Chemical New Materials Technology Co., Ltd.

Relevant to this article

Stereoselective Phenylselenoglycosylation of Glycals Bearing a Fused Carbonate Moiety toward the Synthesis of 2-Deoxy-β-galactosides and β-Mannosides

Doi:10.1021/acs.orglett.0c00732
(2020)
NH₄I-catalyzed chalcogen(S/Se)-functionalization of 5-membered N-heteroaryls under metal-free conditions

Doi:10.1016/j.tet.2018.05.084
(2018)
An efficient synthesis of cytostatic mono and bis-alkynylpyrimidine derivatives by the Sonogashira cross-coupling reactions of 2,4-diamino-6- iodopyrimidine and 2-amino-4,6-dichloropyrimidine

Doi:10.1016/j.tet.2004.04.035
(2004)
Synthesis and phase behavior of liquid crystalline diphenylacetylene derivatives possessing high clearing temperatures

Doi:10.1080/15421400490425784
(2004)
Regioselectivity in the Acid-Catalyzed Isomerization of 2-Substituted 1,4-Dihydro-1,4-epoxynaphthalenes

Doi:10.1021/jo00023a041
(1991)
Synthesis and structure of tetra- and triphenylantimony organosulfonates

Doi:10.1023/B:RUCO.0000011636.28262.d3
(2004)

Article Doi