The reaction of tris(trimethylsilyl)silane with acid chlorides

DOI: 10.1016/S0040-4039(00)91733-7

Source and publish data:

Tetrahedron Letters p. 1787 - 1790 (1992)

Update date:2022-08-03

Topics:

Authors:

Ballestri

Chatgilialoglu

Cardi Cardi

Sommazzi

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Article abstract of DOI:10.1016/S0040-4039(00)91733-7

Tris(trimethylsilyl)silane, in contrast with tributylin hydridge, reduces acid chlorides to the corresponding decarboxylated hydrocarbons via a free radical mechanism. This methodology could be a viable alternative to Barton's decarboxylation reaction.

Full text of DOI:10.1016/S0040-4039(00)91733-7

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