Organometallics p. 2348 - 2350 (1992)
Update date:2022-07-30
Topics:
Barluenga, José
Tomás, Miguel
Ballesteros, Alfredo
Kong, Jian-She
Granda, Santiago García
Pertierra, Pilar
New 1,3,2-diazagermines 2, formed by reaction of 4-amino-1-azabutadienes 1 and diethyl- or diphenylgermanium dichloride, react with dimethyl acetylenedicarboxylate to yield novel 1,5,2-diazagermocines 3 in quantitative yield; the crystal structure of 3a has been determined. The behavior of 3 toward hydrolysis and heating is also reported.
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(2013)
