Tetrahedron Letters p. 2299 - 2302 (1992)
Update date:2022-08-04
Topics: Deprotection Chemoselective Benzyl ethers Benzyl esters Benzyloxymethyl ethers N-benzyl groups Catalytic transfer hydrogenation
Bajwa
-COOBn, -PO(OH)OBn, -O-CBz and N-CBz groups are efficiently and chemoselectively deprotected in the presence of Bn and BOM ethers and N-Bn groups by hydrogenolysis under catalytic transfer hydrogenation using 10% palladium on carbon as the catalyst and cyclohexadiene as the hydrogen donor.
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