Unique Stereocontrol in Lanthanide(III)-Catalyzed Aldol Reactions with the Ketene Silyl Acetal of Methyl (R)-3-Hydroxybutanoate

DOI: 10.1016/S0040-4039(00)91648-4

Source and publish data:

Tetrahedron Letters p. 1465 - 1468 (1992)

Update date:2022-07-29

Topics:

Authors:

Gu, Jin-Hua

Terada, Masahiro

Mikami, Koichi

Nakai, Takeshi

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Article abstract of DOI:10.1016/S0040-4039(00)91648-4

The Eu(III)-catalyzed reaction of α-benzyloxyaldehydes with the (R)-3-hydroxybutanoate-derived ketene silyl acetal is shown to provide a higher level of both "anti" diastereofacial seletion and rather unusual diastereoselection, compared with the conventi

Full text of DOI:10.1016/S0040-4039(00)91648-4

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Product name:(2R,3S)-4-Benzyloxy-3-hydroxy-2-((R)-1-hydroxy-ethyl)-butyric acid methyl ester

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