Addition of Dichlorocarbene on Organic Azides in Solid-Liquid Phase-Transfer Catalysis

DOI: 10.1016/S0040-4039(00)74205-5

Source and publish data:

Tetrahedron Letters p. 2339 - 2342 (1992)

Update date:2022-08-05

Topics:

Authors:

Szoenyi, F.

Cambon, A.

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Article abstract of DOI:10.1016/S0040-4039(00)74205-5

The addition of dichlorocarbene on organic azides in homogeneous medium leads to isocyanide dihalides.In the conditions of the solid-liquid phase transfer catalysis, tetrachloroaziridines and isocyanide dihalides are obtained respectively as main products depending on whether a hydrogenated organic or whether a 2-F-alkylethyl azide is used. Key Words: Azides/ Dichlorocarbene/ Isocyanide dihalide/ Tetrachloroaziridine/ Phase-Transfer Catalysis.

Full text of DOI:10.1016/S0040-4039(00)74205-5

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