Tetrahedron Letters p. 2339 - 2342 (1992)
Update date:2022-08-05
Topics:
Szoenyi, F.
Cambon, A.
The addition of dichlorocarbene on organic azides in homogeneous medium leads to isocyanide dihalides.In the conditions of the solid-liquid phase transfer catalysis, tetrachloroaziridines and isocyanide dihalides are obtained respectively as main products depending on whether a hydrogenated organic or whether a 2-F-alkylethyl azide is used. Key Words: Azides/ Dichlorocarbene/ Isocyanide dihalide/ Tetrachloroaziridine/ Phase-Transfer Catalysis.
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