Tetrahedron Letters p. 5159 - 5162 (1989)
Update date:2022-07-30
Topics:
Haaima, Gerald
Routledge, Anne
Weavers, Rex T.
The (E)-iodoalkylidene lactones which can be formed by reaction of an alkene with N-iodosuccinimide and an acetylenic acid with subsequent free-radical cyclisation, are readily transformed into iodine free akylidene lactones by photolysis.Under different reaction conditions, the photolyses yield mixtures of (E) and (Z)-iodovinylidene lactones.
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(1990)
