Organic and Biomolecular Chemistry p. 900 - 904 (2013)
Update date:2022-08-03
Topics:
Liu, Gang
Zhang, Daming
Li, Jian
Xu, Guangyang
Sun, Jiangtao
A highly efficient enantioselective Darzens reaction of aldehydes with diazoacetamides catalyzed by a (+)-pinanediol-Ti(OiPr)4 system has been developed. The cis-glycidic amides were obtained in high yields and with moderate to excellent enantioselectivity (up to 99%).
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