Novel Crystal Structure of Ytterbium(II)-Benzophenone Dianione Complex and its Reaction with 2,6-Di-tert-butyl-4-methylphenol

DOI: 10.1039/c39920000722

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 722 - 724 (1992)

Update date:2022-08-06

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Authors:

Hou, Zhaomin

Yamazaki, Hiroshi

Kobayashi, Kimiko

Fujiwara, Yuzo

Taniguchi, Hiroshi

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Article abstract of DOI:10.1039/c39920000722

Treatment of 1 equiv. of Yb metal with benzophenone in tetrahydrofuran-hexamethylphosphoramide (hmpa) gives a Yb^II-benzophenone dianion complex, <2> 1 which on treatment with 2,6-di-tert-butyl-4-methylphenol produces t2-2,6-Me-4)2(hmpa)2> 2; both 1 and 2 are structurally characterized by X-ray crystallography.

Full text of DOI:10.1039/c39920000722

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