A Novel and Practical Preparation of α,α-Difluoro Functionalized Phosphonates from Iododifluoromethylphosphonate

DOI: 10.1021/jo00043a027

Source and publish data:

Journal of Organic Chemistry p. 4676 - 4683 (1992)

Update date:2022-07-30

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Authors:

Yang, Zhen-Yu

Burton, Donald J.

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Article abstract of DOI:10.1021/jo00043a027

The addition reaction of iododifluoromethylphosphonate 1 with alkenes is catalyzed by tetrakis(triphenylphosphine)palladium or copper metal under mild conditions.A variety of functional groups, including alkyl, trimethylsilyl, hydroxy, epoxy, acetoxy, ket

Full text of DOI:10.1021/jo00043a027

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