Regio- and Stereoselective Allylic Substitutions of Chiral Secondary Alkylcopper Reagents: Total Synthesis of (+)-Lasiol, (+)-13-Norfaranal, and (+)-Faranal

DOI: 10.1002/anie.201811330

Source and publish data:

Angewandte Chemie - International Edition p. 1509 - 1514 (2019)

Update date:2022-07-30

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Authors:

Skotnitzki, Juri

Spessert, Lukas

Knochel, Paul

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Article abstract of DOI:10.1002/anie.201811330

Chiral secondary alkylcopper reagents were prepared from chiral secondary alkyl iodides by a retentive I/Li exchange followed by a retentive transmetalation with CuBr?P(OEt)₃. Switching the solvent to THF significantly increased their configura

Full text of DOI:10.1002/anie.201811330

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