
Tetrahedron p. 3635 - 3644 (1984)
Update date:2022-07-30
Topics:
Portella, C.
Deshayes, H.
Pete, J. P.
Scholler, D.
Use of HMPT as solvent in photochemistry allows efficient photoreductions.Alkyl esters and especially non absorbing alkyl acetates are photoreduced in excellent yields into alkanes.In the latter case, a protonating agent is necessary.Numerous examples illustrate the generality and convenience of the reaction.This photoreduction involves an electron transfer from HMPT to ester.
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