A Short Enantiospecific Route to Isodaucane Sesquiterpenes from Limonene. On the Absolute Configuration of (+)-Aphanamol I and II

DOI: 10.1021/jo00046a018

Source and publish data:

Journal of Organic Chemistry p. 5370 - 5376 (1992)

Update date:2022-07-30

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Authors:

Hansson, Thomas

Wickberg, Boerje

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Article abstract of DOI:10.1021/jo00046a018

The isodaucane sesquiterpenes (+)-aphanamol I (3) and (-)-2-oxoisodauc-5-en-12-al <(-)-6> have been prepared in a short reaction sequence from 5(S)-isopropyl-2-methyl-1-cyclopentene-1-carbaldehyde (S)-23 (readily obtainable from (+)-limonene).Key steps we

Full text of DOI:10.1021/jo00046a018

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