Chemical and Pharmaceutical Bulletin p. 1343 - 1345 (1992)
Update date:2022-09-26
Topics:
Murase
Hosaka
Yoshida
Tobinaga
Reactivities of a new diene N,N-dimethylamino-3-methylthiobutadiene (7), prepared in situ by treatment of the methiodide of thioenaminone 5 with triethylamine, with several dienophiles as a Diels-Alder diene, were investigated. In general, the cycloaddition reactions were completed at low temperature for short periods, which showed that the diene has a high reactivity as a Diels-Alder diene.
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