A New Route to Planar-chiral Cyclopentadienyl-Iron(II) and -Rhodium(I) Complexes

DOI: 10.1039/c39920000964

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 964 - 965 (1992)

Update date:2022-08-03

Topics: Chiral Ligands Synthesize Complexes Coordination Iron(II) Cyclopentadienyl Route Planar-chiral

Authors:

Uno, Mitsunari

Ando, Katsuhiro

Komatsuzaki, Nobuko

Takahashi, Shigetoshi

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Article abstract of DOI:10.1039/c39920000964

Diastereoisomerically pure planar-chiral cyclopentadienyl-metal complexes, 3 and 4, are prepared by the reaction of the cyclopentadiene 2 having a (-)-menthyl group with FeCl2 or 2 (cod=cycloocta-1,5-diene); removal of the (-)-menthyl group fro

Full text of DOI:10.1039/c39920000964

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Product name:1-<(1R,2S,5R)-menthoxycarbonyl>-2-methyl-4-phenyl-1,3-cyclopentadiene

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