Michael addition of formaldehyde dimethylhydrazone to nitroolefins. A new formyl anion equivalent

DOI: 10.1016/S0040-4039(00)92538-3

Source and publish data:

Tetrahedron Letters p. 3691 - 3694 (1992)

Update date:2022-08-02

Topics:

Authors:

Lassaletta, Jose-Maria

Fernandez, Rosario

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)92538-3

Formaldehyde dimethylhydrazone readily adds to simple nitro-olefins in the absence of base giving β-nitrodimethylhydrazones in very high yields. The corresponding β-nitroaldehydes can be obtained by ozonolysis.

Full text of DOI:10.1016/S0040-4039(00)92538-3

Products guided by the article

Product name:N,N-Dimethyl-N'-[3-nitro-2-phenyl-prop-(E)-ylidene]-hydrazine

Cas No:143357-63-5

R&D Labs maybe for 143357-63-5

Weifang Dongxing Chitosan Factory

website:http://dxchitosan.lookchem.com/

Contact:13475651157

Address:Weifang city ,shandong province
Hubei ShiNan Pharmaceutical Chemical co., Ltd.(expird)

Contact:+86-13554447107

Address:Wuhan HongShanOu wu no road 378 future residence building 1 unit 14 layer no. 1401 A
hangzhou verychem science and technology co.ltd

website:http://www.verypharm.com

Contact:+86-571-88162785; 88162786

Address:F1502, 753 Shenhua road, Hangzhou, China
Suzhou Lixin Pharmaceutical Co., Ltd.

Contact:86-512-88169812

Address:21 Tangxi Road, Suzhou New District, Suzhou 215151
Zhejiang Haizhou Pharmaceutical Co., Ltd.

website:https://www.haizhoupharma.com/

Contact:+86-576-88221016

Address:No. 19, Donghai 5th Avenue, Yanhai Industrial Zone, Linhai, Zhejiang, China

Relevant to this article

Synthesis of Combretastatin D-2⁺

Doi:10.1016/S0040-4039(00)74692-2
(1992)
Iodonium ion-assisted glycosylation of alkyl (aryl) 1-thio-glycosides: Regulation of stereoselectivity and reactivity

Doi:10.1016/0008-6215(91)84036-E
(1991)
Catalytic Asymmetric Synthesis of Optically Active Secondary Alcohols Deuterated on the Secondary Carbon by the Enantioselective Alkylation of Aldehydes

Doi:10.1246/bcsj.65.1734
(1992)
Catalytic Asymmetric Synthesis with Trans-Chelating Chiral Diphosphine Ligand TRAP: Rhodium-Catalyzed Asymmetric Michael Addition of α-Cyano Carboxylates

Doi:10.1021/ja00047a053
(1992)
Iron(III)-catalyzed highly efficient, one-pot synthesis of triazolo[1,2-a]indazoletriones and spirotriazolo[1,2-a]indazoletetraones

Doi:10.1246/cl.130164
(2013)
Catalytic asymmetric one-pot synthesis of α-methylene-γ-lactams

Doi:10.1016/j.tet.2013.11.028
(2014)

Article Doi