A Peptide-Aluminum Complex as a Novel Chiral Lewis Acid. Asymmetric Addition of Cyanotrimethylsilane to Aldehydes

DOI: 10.1021/jo00051a020

Source and publish data:

Journal of Organic Chemistry p. 6778 - 6783 (1992)

Update date:2022-08-02

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Authors:

Ohno, Hiroshi

Nitta, Hideaki

Tanaka, Kenzo

Mori, Atsunori

Inoue, Shohei

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Article abstract of DOI:10.1021/jo00051a020

The enantioselective addition of cyanotrimethylsilane (TMSCN) to aldehydes promoted by the addition of a stoichiometric or catalytic amount of organoaluminum complexes of dipeptide esters or α-amino acid amides whose amino terminals are modified by a vari

Full text of DOI:10.1021/jo00051a020

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