Total synthesis of (-)-dactylyne and (-)-isodactylyne

DOI: 10.1016/S0040-4039(00)74257-2

Source and publish data:

Tetrahedron Letters p. 4349 - 4352 (1992)

Update date:2022-07-30

Topics:

Authors:

Gao Gao

Murai Murai

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Article abstract of DOI:10.1016/S0040-4039(00)74257-2

The first total synthesis of (-)-dactylyne (1) and (-)-isodactylyne (2), which are isolated from sea hare, is described via intermediates 3-15 and 17-18. Critical steps in the synthesis include a stereoselective construction as well as an intramolecular r

Full text of DOI:10.1016/S0040-4039(00)74257-2

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Product name:2,2-Dimethyl-propionic acid (3R,4R)-4-bromo-3-(tert-butyl-dimethyl-silanyloxy)-5-{(2R,3R)-3-[(R)-1-hydroxy-2-(4-methoxy-benzyloxy)-ethyl]-oxiranyl}-pentyl ester

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