Stereoelectronic Control of Facial Selectivity in the Diels-Alder Cycloaddition of Sterically Unbiased 5,5-Diarylcyclopentadienes

DOI: 10.1021/jo00047a009

Source and publish data:

Journal of Organic Chemistry p. 5585 - 5589 (1992)

Update date:2022-08-03

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Authors:

Halterman, Ronald L.

McCarthy, Bridget A.

McEvoy, Marjorie A.

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Article abstract of DOI:10.1021/jo00047a009

This study provides strong evidence for stereoelectronic control of diastereoselectivity in the Diels-Alder cycloaddition of sterically unbiased 5-(4-X-phenyl)-5-phenylcyclopentadienes 1 (X = NO2, Cl, and N(CH3)2) with dimethyl acetylenedicarboxylate (DMA

Full text of DOI:10.1021/jo00047a009

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