Asymmetric Aldol Reactions of an α-Benzoyl Titanium Enolate

DOI: 10.1016/0040-4020(92)80021-7

Source and publish data:

Tetrahedron p. 5701 - 5708 (1992)

Update date:2022-08-05

Topics:

Authors:

Choudhury, Anusuya

Thornton, Edward R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(92)80021-7

Diastereofacial selectivities of 97-99.7 percent can be conveniently obtained in aldol reactions of the chiral titanium enolate derived from the ketone C2H5COCH(OCOPh)cyclo-C6H11, with representative aldehydes.

Full text of DOI:10.1016/0040-4020(92)80021-7

Products guided by the article

Product name:(1S,3S,4S)-1-Benzoyloxy-1-cyclohexyl-4-hydroxy-3-methyl-4-phenylbutan-2-one

Cas No:143955-06-0

R&D Labs maybe for 143955-06-0

JiYi Chemical (Beijing) Co., Ltd.

Contact:+86-10-89385733

Address:Shilou Town of Fangshan District， Beijing
SHIJIAZHUANG AGERUO-BIOTECH CO.LTD

Contact:+86-130-2866-6699

Address:Huaian east Road 158
Tianjin Te-An Chemtech Co., Ltd.(expird)

Contact:+86-22-65378638

Address:A5-8, No.80 Haiyun Street, TEDA
Shanghai Korey Pharm Co.,Ltd.(expird)

Contact:021-61840961 021-61840962

Address:No.157,Zhuguang Rd, Qingpu, Shanghai, China
SHIFANG SUHONG CHEMICAL CO.,LTD

Contact:+86-838-2224563

Address:Room 1207 Zongchen Sunshine No.128 Taishan South Road,Deyang City,Sichuan China

Relevant to this article

Enantioselective synthesis of quaternary α-amino acids via l -tert-leucine-derived squaramide-catalyzed conjugate addition of α-nitrocarboxylates to enones

Doi:10.1021/acs.joc.6b00543
(2016)
Synthesis of Amino-Containing Phosphines. The Use of Iminophosphorane as a Protecting Group for Primary Amines

Doi:10.1021/jo00048a057
(1992)
Structural alterations in desferrioxamine compatible with iron clearance in animals

Doi:10.1021/jm00103a012
(1992)
Synthesis and structures of copper(II), copper(I,II) and copper(I) complexes with 4-(3,5-diphenyl-1H-pyrazol-1-yl)-6-(piperidin-1-yl)pyrimidine. Luminescence of copper(I) complexes

Doi:10.1016/j.poly.2013.04.009
(2013)
Ti-TADDOLate-Catalyzed, Highly Enantioselective Addition of Alkyl- and Aryl-Titanium Derivatives to Aldehydes

Doi:10.1016/S0040-4020(01)90475-2
(1994)
Preparation of TCPP: Block copolymer composites and study of their memory behavior by tuning the loading ratio of TCPP in the polymer matrix

Doi:10.1039/c3tc30359d
(2013)

Article Doi