Asymmetric Aldol Reactions of an α-Benzoyl Titanium Enolate

DOI: 10.1016/0040-4020(92)80021-7

Source and publish data:

Tetrahedron p. 5701 - 5708 (1992)

Update date:2022-08-05

Topics:

Authors:

Choudhury, Anusuya

Thornton, Edward R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(92)80021-7

Diastereofacial selectivities of 97-99.7 percent can be conveniently obtained in aldol reactions of the chiral titanium enolate derived from the ketone C2H5COCH(OCOPh)cyclo-C6H11, with representative aldehydes.

Full text of DOI:10.1016/0040-4020(92)80021-7

Products guided by the article

Product name:(1S,3S,4S)-1-Benzoyloxy-1-cyclohexyl-4-hydroxy-3-methyl-4-phenylbutan-2-one

Cas No:143955-06-0

R&D Labs maybe for 143955-06-0

JIEJIE GROUP CO.,LTD.

Contact:+86 021-51698675

Address:1701, Jielong Plaza, No.618 Pingliang Rd, ShangHai,China
Wuxi Olite Chemical Co., Ltd.

Contact:86-510-82853889

Address:Rm.3732, No.18-2,Yonghe Rd.,Wuxi,Jiangsu,214023,China
Raspberry Inter （jiangsu） Co., Ltd.

Contact:+86-523-86200360/+86-523-86200361

Address:North Side Chuangye Road Gaogang Taizhou
Shanghai Kangxin Chemical Co., Ltd

Contact:+86 21 60717227

Address:118,Ganbai Village,Waigang Town,Jiading District,Shanghai
Shanghai Longjin Metallic Material Co., Ltd.

website:http://www.shlongjin.cn/

Contact:021-56517503,56502257

Address:No.16, Lane 555, Chengyin Road, Shanghai

Relevant to this article

Enantioselective synthesis of quaternary α-amino acids via l -tert-leucine-derived squaramide-catalyzed conjugate addition of α-nitrocarboxylates to enones

Doi:10.1021/acs.joc.6b00543
(2016)
Synthesis of Amino-Containing Phosphines. The Use of Iminophosphorane as a Protecting Group for Primary Amines

Doi:10.1021/jo00048a057
(1992)
Structural alterations in desferrioxamine compatible with iron clearance in animals

Doi:10.1021/jm00103a012
(1992)
Synthesis and structures of copper(II), copper(I,II) and copper(I) complexes with 4-(3,5-diphenyl-1H-pyrazol-1-yl)-6-(piperidin-1-yl)pyrimidine. Luminescence of copper(I) complexes

Doi:10.1016/j.poly.2013.04.009
(2013)
Ti-TADDOLate-Catalyzed, Highly Enantioselective Addition of Alkyl- and Aryl-Titanium Derivatives to Aldehydes

Doi:10.1016/S0040-4020(01)90475-2
(1994)
Preparation of TCPP: Block copolymer composites and study of their memory behavior by tuning the loading ratio of TCPP in the polymer matrix

Doi:10.1039/c3tc30359d
(2013)

Article Doi