Rhodium(II) catalyzed asymmetric cyclopropanation of glycals with ethyl diazoacetate

DOI: 10.1016/0957-4166(95)00418-1

Source and publish data:

Tetrahedron Asymmetry p. 49 - 52 (1996)

Update date:2022-08-05

Topics:

Authors:

Timmers, Cornelis M.

Leeuwenburgh, Michiel A.

Verheijen, Jeroen C.

Van Der Marel, Gijsbert A.

Van Boom, Jacques H.

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Article abstract of DOI:10.1016/0957-4166(95)00418-1

Carbenoid species generated from ethyl diazoacetate and catalytic Rh₂(OAc)₄ react smoothly and with a high degree of stereoselectivity with glycals resulting in the predominant formation of doubly branched adducts containing an α-exo

Full text of DOI:10.1016/0957-4166(95)00418-1

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