An efficient rearrangement of secondary alkyl S-methyl xanthates by trimethylaluminum (TMA)

DOI: 10.1016/0040-4039(96)00339-5

Source and publish data:

Tetrahedron Letters p. 2695 - 2698 (1996)

Update date:2022-08-04

Topics:

Authors:

Barton, Derek H. R.

Choi, Seung-Yong

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Article abstract of DOI:10.1016/0040-4039(96)00339-5

The rearrangement of secondary S-methyl xanthates to S-methyl dithiocarbonates at room temperature using trimethylaluminum has been studied. This reaction affords an efficient and simple method for converting secondary alcohols to thiols.

Full text of DOI:10.1016/0040-4039(96)00339-5

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