Metal-Promoted Thiyl Radical Cylizations in β-Lactam Antibiotics

DOI: 10.1016/S0040-4039(00)61285-6

Source and publish data:

Tetrahedron Letters p. 4783 - 4786 (1992)

Update date:2022-09-26

Topics:

Authors:

Cabri, Walter

Candiani, Ilaria

Bedeschi, Angelo

Santi, Roberto

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Article abstract of DOI:10.1016/S0040-4039(00)61285-6

Intramolecular thiyl radical addition to a double bond promoted by Fe(III) and Mn(III) is described.The stabilized radical intermediate afforded by subsequent hydrogen abstraction cephams 4 and 5. Key words: thiol; radical cyclization; iron; manganese.

Full text of DOI:10.1016/S0040-4039(00)61285-6

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