Stereocontrolled synthesis of either trans- or cis-trimethylsilylvinyloxiranes via sulfonium ylides

DOI: 10.1039/cc9960001353

Source and publish data:

Chemical Communications p. 1353 - 1354 (1996)

Update date:2022-07-29

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Authors:

Zhou, Yong-Gui

Li, An-Hu

Hou, Xue-Long

Dai, Li-Xin

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Article abstract of DOI:10.1039/cc9960001353

trans- or cis-β-Trimethylsilylvinyloxiranes are prepared by the reaction of aldehydes with a 3-trimethylsilylated dimethylsulfonium allylide under phase-transfer conditions or with a preformed 3-trimethylsilylated diphenylsulfonium allylide in the presenc

Full text of DOI:10.1039/cc9960001353

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Product name:[(E)-2-((2R,3R)-3-Cyclohexyl-oxiranyl)-vinyl]-trimethyl-silane

Cas No:144541-55-9

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