
Organometallics p. 4726 - 4729 (2013)
Update date:2022-07-29
Topics:
Choy, Sandra W. S.
Page, Michael J.
Bhadbhade, Mohan
Messerle, Barbara A.
A large increase in reaction rate was observed for the catalyzed mono- and dihydroalkoxylation of alkynes when structurally constrained bimetallic Rh(I) catalysts with imidazolyl-imine ligands were compared to their monometallic analogues. The "cooperative" enhancement was vastly improved by restricting the conformational freedom of the bimetallic structure and minimizing the intermetallic Rh···Rh distance.
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