Organic and Biomolecular Chemistry p. 4488 - 4502 (2013)
Update date:2022-08-04
Topics:
McAdam, Catherine A.
McLaughlin, Mark G.
Johnston, Adam J. S.
Chen, Jun
Walter, Magnus W.
Cook, Matthew J.
A facile and user-friendly protocol has been developed for the selective synthesis of E-vinyl silanes derived from propargylic alcohols using a PtCl 2/XPhos catalyst system. The reaction is generally high yielding and provides a single regioiso
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