ENANTIOMERIC SYNTHESIS OF POLYHYDROXYLATED INDOLIZIDINE ANALOGUES RELATED TO CASTANOSPERMINE: 1-DEOXY-7-EPICASTANOSPERMINE AND 1,7-DIDEOXY-7-FLUOROCASTANOSPERMINE

DOI: 10.1016/S0040-4020(01)86601-1

Source and publish data:

Tetrahedron p. 8541 - 8544 (1992)

Update date:2022-08-03

Topics:

Authors:

Lee, C.-Kuan

Sim, K. Y.

Zhu, Jun

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Article abstract of DOI:10.1016/S0040-4020(01)86601-1

(6S,7S,8R,8aR)-6,7,8-Trihydroxyindolizidine (1) and its (7R)-deoxyfluoro analogue (2) was synthesised from 5,8-benzyloxycarbonylimino-5,6,7,8-tetradeoxy-1,2-O-isopropylidene-α-D-gluco-octose (3).The key step is an oxidation-reduction sequence.Introduction

Full text of DOI:10.1016/S0040-4020(01)86601-1

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