Helvetica Chimica Acta p. 1212 - 1220 (1982)
Update date:2022-08-03
Topics:
Mueller, Paul
Blanc, Jacky
Lenoir, Dieter
The rates of oxidation with chromic acid of 15 bi- and polycyclic secondary alcohols have been measured and correlated with strain changes calculated by the MM1-program between the alcohols and the corresponding ketones.A correlation of the same quality is obtained upon representation of OH-strain by CH3-strain.The significance of the correlations with respect to the oxidation mechanism as well as the limitations of the applicability of force-field calculations to reactivity problems are discussed.
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Doi:10.1002/chem.201300100
(2013)Doi:10.1039/c6ra10467c
(2016)Doi:10.1135/cccc19921466
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(2013)Doi:10.3987/COM-12-S(N)30
(2012)Doi:10.1016/j.tet.2013.05.090
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