Helvetica Chimica Acta p. 1212 - 1220 (1982)
Update date:2022-08-03
Topics:
Mueller, Paul
Blanc, Jacky
Lenoir, Dieter
The rates of oxidation with chromic acid of 15 bi- and polycyclic secondary alcohols have been measured and correlated with strain changes calculated by the MM1-program between the alcohols and the corresponding ketones.A correlation of the same quality is obtained upon representation of OH-strain by CH3-strain.The significance of the correlations with respect to the oxidation mechanism as well as the limitations of the applicability of force-field calculations to reactivity problems are discussed.
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Doi:10.1002/chem.201300100
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